Protective wax for bleached teeth

ABSTRACT

A protective coating material applied to whitened or bleached teeth. The protective coating material comprises microcrystalline wax, mineral oil, vitamin E, and amorphous calcium phosphate or ACP. The protective coating material covers the whitened or bleached tooth surface protecting it from staining thereby prolonging the whiteness of the teeth. The whitened or bleached damaged tooth enamel may also be strengthened or repaired.

RELATED APPLICATIONS

This application is a continuation of International ApplicationPCT/US2013/043504, with an international filing date of May 31, 2013,which claims the benefit of U.S. Provisional Application No. 61/654,578filed Jun. 1, 2012, all of which are herein incorporated by reference.

FIELD OF THE INVENTION

The present invention relates in general to protecting and repairingteeth that have been bleached, and particularly to a protective waxcoating that maintains, protects, repairs, and preserves bleached teethprolonging their white appearance.

BACKGROUND OF THE INVENTION

The public today is concerned about their appearance, youth, andespecially about their smile. There is much that has been accomplishedin dentistry today that enhances the ability of the teeth to becomewhite as the teeth once were in the persons youth. This can beaccomplished by the use of crowns, veneers and bleaching. As a result,cosmetic dentistry has become very popular. Many people would like tohave whiter and brighter teeth. As a result whitening or bleaching ofteeth has become very common. However, all these means require asubstantial investment on the part of the person.

The maintenance of the crowns and veneers, once they have been restoredwith porcelain, is slight because of the sealed surface of theporcelain. This is not true of natural teeth that have been whitened orbleached. The surface of bleached teeth reveals a surface that is fullof cracks and crevices that is the result of the bleaching process.Therefore, these damaged surfaces are able to easily pickup pigmentsthat are in our food and habits. Some of these pigments or stainingproducts are; red wine, coffee, tea, lipstick, nicotine from smoking,food with any color. All these things have a tendency to stain and colorthe teeth that have been bleached. The solution to this is to re-bleachthese teeth. The problem is that this will cause further damage to thepreviously bleached enamel and continual bleaching may lead to seriousdamage to the teeth and even result in the need for a root canal inorder to save them.

Generally, the tooth bleaching process uses a form of hydrogen peroxidewhich whitens, and oxidizes the enamel of the tooth opening the enamelpermitting it to be easily stained. In order to maintain their whitenessteeth must be periodically bleached. Repeated bleaching may potentiallydamage the enamel of the teeth. Often this damage creates pits andfissures in the enamel resulting in porosity that results in the teethbeing more easily stained and discolored.

There have been coatings placed on teeth in an effort to provide abacteria inhibiting film. One such protective coating is disclosed inU.S. Pat. No. 5,665,333 entitled “Methods, Compositions, and DentalDelivery Systems for the Protection of the Surface of Teeth”, issuing toHomola et al. on Sep. 9, 1997, which is herein incorporated byreference. Therein disclosed is a protective coating particularlyadapted to provide a bacteria inhibiting film on the surface of a tooth.A transfer agent and barrier material is used to improve the adhesion ofthe protective coating on the surface of the tooth.

Other coatings or materials have also been applied to teeth. One suchmaterial is amorphous calcium phosphate or ACP which has been applied toteeth to remineralize the teeth. The use of a ACP to remineralize teethis disclosed in U.S. Pat. No. 5,037,639 entitled “Methods andCompositions for Mineralizing Calcified Tissues” issuing to Tongue onAug. 6, 1991, which is herein incorporated by reference. Thereindisclosed is a method of applying a composition containing amorphouscalcium phosphate or ACP to teeth to remineralize the teeth.

While the prior protective coatings are well adapted to provide abacteria inhibiting film or remineralizing of teeth, they are notnecessarily suitable for use in maintaining whiter teeth and protectingwhitened teeth. Therefore, there is a need to provide a protectivecoating specifically adapted for maintaining the whiteness of teeth andprotecting them from damage when they have been bleached.

SUMMARY OF THE INVENTION

The present invention is a protective coating applied to teeth that havebeen whitened that maintains their whiteness and helps to repair damagecaused by the whitening or bleaching of the teeth. A microcrystallinewax is mixed with vitamin E, mineral oil, and amorphous calciumphosphate providing a smooth consistent wax material that may be easilyapplied to whitened teeth. The protective coating prevents staining andthe amorphous calcium phosphate helps to repair the damaged toothsurface caused by the repeated whitening of the teeth.

Accordingly it is an object of the present invention to maintain thecolor of whitened teeth.

It is another object of the present invention to extend the time betweenteeth whitening procedures.

It is yet another object of the present invention to protect teeth andrepair damage to teeth that have been whitened.

It is an advantage of the present invention that it reduces the need torepeatedly whiten teeth.

It is another advantage of the present invention that it is easy toapply to the teeth.

Is a feature of the present invention that it has a creamy consistencyand is easy to apply.

It is another feature of the present invention that it containsamorphous calcium phosphate.

These and other objects, advantages, and features will become morereadily apparent in view of the following more detailed description.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 schematically illustrates the present invention applied to atooth surface.

FIG. 2 is a highly magnified image of tooth enamel that has not beenbleached.

FIG. 3 is a highly magnified image of tooth enamel that has beenbleached.

FIG. 4 is a highly magnified image of tooth enamel that has been treatedwith the protective wax of the present invention.

FIG. 5 is a magnified image of tooth enamel that has been partiallytreated with the protective wax of the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The present invention is a protective coating material specificallyadapted for maintaining and protecting bleached teeth so as to seal andprevent teeth from being exposed to stains. The protective coatingmaterial of the present invention is easy to apply and adheres to theteeth for a prolonged period of time. The present invention also mayhelp to strengthen tooth enamel and possibly reverse the damage causedby bleaching. The present invention uses a mixture of microcrystallinewax, oils, such as vitamin E and mineral oil, amorphous calciumphosphate, and aromatic or flavoring oils such as peppermint. Amorphouscalcium phosphate is a material that has been shown to repair damagedtooth enamel. The microcrystalline wax has fine crystals and is tackierand more elastic than paraffin waxes. Therefore, the microcrystallinewax is particularly well-suited for applying to teeth.

A preferred formulation that has proven to work particularly well onbleached teeth is described below.

The process of making the protective coating material consisted ofheating and melting 30 grams of microcrystalline wax to a temperature of180° C. Once the microcrystalline wax was melted, 12 mL of vitamin Ewere mixed until the mixture was water clear. 40 mL of mineral oil wasadded to the melted wax and mixed until water clear. The wax mixture wastaken off the heat and 1 gram of amorphous calcium phosphate dissolvedin 2 to 4 mL of acetone was added. The solution of amorphous calciumphosphate was poured into the wax mixture and stirred until the mixturewas uniformly white in color and the wax mixture began to solidify. Thewax mixture was then cooled and solidified to a creamy consistency.

In another procedure or method of making the protective coatingmaterial, the amorphous calcium phosphate, rather than being dissolvedin the acetone, may be dissolved in the mineral oil. This eliminates theneed for the acetone.

After cooling the protective coating material is applied in a thin coatto the bleached teeth. The protective coating material can be applied byany means, such as a brush, Q-tip, or any other applicator to evenlydistribute the protective coating material to the bleached teeth. Theprotective coating material may also be applied by a finger orlipstick-like container. The protective coating material may be appliedonce every two to three days to protect the teeth and prevent the teethfrom staining so as to maintain their whiteness.

The table below indicates the desired formulation for a protectivecoating material that has proven to work especially well in protectingand maintaining teeth white after whitening or bleaching.

PERCENT BY WEIGHT MATERIAL 35 to 45%, preferably Microcrystalline waxsubstantially 39% 10 to 20%, preferably Vitamin E substantially 15% 40to 50%, preferably Mineral Oil substantially 45% 0.5 to 1.5%, preferablyAmorphous Calcium Phosphate substantially 1% (ACP) .0005 to .001%,preferably a Flavoring trace amount

The formulation indicated in the above table has proven to result in adesirable consistency and color or transparency of the protectivecoating material. However, it should be appreciated that the formulationmay be modified as desired to provide a desired consistency or texturefor a particular circumstance or application. Accordingly, if the oilcontent is reduced the viscosity and hardness will increase and may makethe protective coating material more difficult to apply. If theamorphous calcium phosphate, ACP, is increased an opaque protectivecoating material may result changing the color of the teeth. If the oilcontent is increased the protective coating material may become runnyand unmanageable.

The protective coating material of the present invention greatlyfacilitates the maintaining of white teeth and prevents the need forfrequent repeated bleaching, which may damage the teeth.

Studies have been performed in which the protective coating material ofthe invention has prevented teeth from staining. The protective coatingmaterial of the present invention is safe and can be easily applied byan individual. The protective coating material of the invention may besold in a kit together with or without a tooth whitening or bleachingmaterial.

FIG. 1 illustrates the protective coating material applied to a tooth.In FIG. 1 a tooth 10 has a tooth surface 12. The tooth surface 12 oftenhas irregularities or bleach damage 14 caused by bleaching. Theirregularities or bleach damage 14 may be comprised of small pits andfissures or simply porosity of the tooth 10 enamel. The protectivecoating material 16 is illustrated applied to the tooth surface 12 witha brush 18. The protective coating material 16 acts as a barrier tostains adhering to the tooth surface 12. Additionally, the protectivecoating material 16 greatly assists and facilitates the protection andrepair of the bleached damaged tooth enamel.

FIG. 2 is a picture of highly magnified untreated tooth enamel takenwith a scanning electron microscope, SEM. As can be seen in FIG. 2,untreated tooth enamel is relatively smooth with a surface resistant tostaining or discoloration.

FIG. 3 is a picture of highly magnified whitened or bleached toothenamel taken with a scanning electron microscope, SEM. As can be seen inFIG. 3, the whitened or bleached tooth enamel is rough and has anirregular surface with the enamel rod ends exposed by the whitening orbleaching of the tooth enamel. In this condition the tooth enamel isvery susceptible to staining or discoloration.

FIG. 4 is a picture of highly magnified protective coating material ofthe present invention applied to whitened or bleached tooth enamel takenwith a scanning electron microscope, SEM. As can be seen in FIG. 4, theprotective coating wax material fills in and covers the rough orirregular surface of the whitened bleached tooth enamel providing asmooth even coating.

FIG. 5 is a picture of magnified whitened or bleached tooth enamel, onthe left, and the protective coating wax material applied to thewhitened or bleached tooth enamel, on the right. The picture in FIG. 5has a magnification substantially less than the pictures in FIGS. 2-4.The uncoated whitened or bleached tooth enamel on the left has a damagedroughened or uneven surface with the enamel rods showing. The coatedwhitened or bleached enamel, on the right, illustrates the protectivecoating material covering the damaged roughened or uneven surface andthe exposed enamel rods of the whitened or bleached tooth enamel.

The invention provides a simple relatively easily manufacturedprotective material coating that is easily and safely applied towhitened teeth so as to prolong their whiteness. The invention is safeand effective and can be applied as often as desired in order tomaintain whiter teeth. The invention may also repair damaged toothenamel to 2 the harsh chemicals used in whitening teeth. The protectivematerial coating may also be provided together with a whitening agent ina single package or kit as a convenience to the user.

While the preferred embodiments and methods of the present inventionhave been shown and described herein, it will be apparent to thoseskilled in the art that various modifications and variations may be madewithout departing from the spirit and scope of the invention as claimedherein.

What is claimed is:
 1. A method of maintaining whiter teeth afterwhitening comprising the step of: applying a protective coating materialto the teeth after bleaching.
 2. A method of maintaining whiter teethafter whitening as in claim 1 wherein: the protective coating materialcomprises amorphous calcium phosphate.
 3. A method of maintaining whiterteeth after whitening as in claim 1 wherein: the protective coatingmaterial comprises, a microcrystalline wax; an oil; and amorphouscalcium phosphate.
 4. A method of maintaining whiter teeth afterwhitening as in claim 3 wherein: the protective coating material furthercomprises, vitamin E.
 5. A method of maintaining whiter teeth comprisingthe steps of: applying a whitening material to teeth; and applying aprotective coating material to the teeth after the step of applying thewhitening material.
 6. A method of maintaining whiter teeth as in claim5 wherein: the protective coating material comprises, a microcrystallinewax; vitamin E; mineral oil; and amorphous calcium phosphate.
 7. Amethod of maintaining whiter teeth as in claim 6 wherein: themicrocrystalline wax is between 35% and 45% by weight; the vitamin E isbetween 10% and 20% by weight; the mineral oil is between 40% and 45% byweight; and the amorphous calcium phosphate is between 0.5% and 1.5% byweight.
 8. A method of maintaining whiter teeth as in claim 7 wherein:the microcrystalline wax is substantially 39% by weight; the vitamin Eis substantially 15% by weight; the mineral oil is substantially 45% byweight; and the amorphous calcium phosphate is 1% by weight.
 9. A methodof maintaining whiter teeth as in claim 5 wherein: the protectivecoating material further comprises a flavoring.
 10. A method of making aprotective coating material used for coating teeth after bleachingcomprising the steps of: melting microcrystalline wax; mixing an oilinto the melted microcrystalline wax forming a wax mixture; dissolvingamorphous calcium phosphate in a solvent forming an amorphous calciumphosphate solution; and pouring the amorphous calcium phosphate solutioninto the wax mixture until the wax mixture is uniformly white in colorand the wax mixture begins to solidify, whereby the protective coatingmaterial having a creamy consistency is formed.
 11. A method of making aprotective coating material used for coating teeth after bleaching as inclaim 10 wherein: the oil comprises mineral oil.
 12. A method of makinga protective coating material used for coating teeth after bleaching asin claim 10 further comprising the step of: mixing in vitamin E aftersaid step of melting microcrystalline wax.
 13. A method of making aprotective coating material used for coating teeth after bleachingcomprising the steps of: melting microcrystalline wax; dissolvingamorphous calcium phosphate in an oil forming an amorphous calciumphosphate solution; mixing the oil and dissolved amorphous calciumphosphate into the melted microcrystalline wax forming a wax mixture;and pouring the amorphous calcium phosphate solution into the waxmixture until the wax mixture is uniformly white in color and the waxmixture begins to solidify, whereby the protective coating materialhaving a creamy consistency is formed.
 14. A method of making aprotective coating material used for coating teeth after bleaching as inclaim 13 wherein: the oil comprises mineral oil.
 15. A method of makinga protective coating material used for coating teeth after bleaching asin claim 13 further comprising the step of: mixing in vitamin E aftersaid step of melting microcrystalline wax.
 16. A protective coatingmaterial for use on teeth after whitening comprising: a microcrystallinewax; an oil; and amorphous calcium phosphate.
 17. A protective coatingmaterial for use on teeth after whitening as in claim 16 furthercomprising: vitamin E.
 18. A protective coating material for use onteeth after whitening as in claim 17 wherein: said microcrystalline waxis between 35% and 45% by weight; said vitamin E is between 10% and 20%by weight; said mineral oil is between 40% and 45% by weight; and saidamorphous calcium phosphate is between 0.5% and 1.5% by weight.
 19. Akit for maintaining teeth white comprising: a tooth whitening agent; anda protective coating material, whereby after whitening the teeth theprotective coating material is applied protecting the teeth.
 20. A kitfor maintaining teeth white as in claim 19 wherein: said protectivecoating material comprises, a microcrystalline wax; an oil; andamorphous calcium phosphate.